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Sandra Signorella, Verónica Daier, Silvia Garcı́a, Roxana Cargnello, Juan Carlos González, Marcela Rizzotto, Luis F Sala.European Journal of Inorganic Chemistry 1999, 1999 Kinetics and Mechanism of the Outer-Sphere Oxidation of Horse-Heart Cytochromec by an Anionic Chromium(v) Complex – Kinetic Evidence for Precursor Formation and a Late Electron-Transfer Transition State. A comparative kinetic and mechanistic study. The reduction of CrVI to CrIII by the α and β anomers of d-glucose in dimethyl sulfoxide. Sandra Signorella, Rubén Lafarga, Verónica Daier, Luis F.Chromium redox couples for application to redox flow batteries. Micellar effect on the kinetics and mechanism of chromium(VI) oxidation of organic substrates. Mechanistic studies of relevance to the biological activities of chromium. Journal of Sol-Gel Science and Technology 2005, 36 Reduction of Cr(VI) Assisted by Sol-Gel Generated Electron-Hole Centers. Electrocatalytic reduction of platinum phosphate blue on carbon surfaces: A novel method for preparing fuel cell electrodes. Oxidation of Hydrazine in Aqueous Solution. Chromium(VI) oxidants having quaternary ammonium ions: studies on synthetic applications and oxidation kinetics. Journal of the Turkish Chemical Society, Section A: Chemistry 2017,, 931-952. Electrochemistry and sensitive determination of a metal complex azo dye using graphite paste electrode modified with Na-bentonite. Magnetic Characterization of Chromium Intermediates in the Reduction of Chromium (VI) by Glutathione in Acidic Solutions. Roberto Marín, Rathindra Bose, Bogdan Dabrowski, Stanislaw Kolesnik.Fabrication of visible-light-active MR/NH2-MIL-125(Ti) homojunction with boosted photocatalytic performance. Yangjie Fu, Kejie Zhang, Yi Zhang, Yanqing Cong, Qi Wang.The Journal of Organic Chemistry 1998, 63 Oxygenation Reaction of Organic Sulfides with Oxochromium(V) Ion. Tharumeya Kuppusamy Ganesan, Seenivasan Rajagopal, Jesuraja Bosco Bharathy, and, Ambalam I.Heterolytic Activation of C–H Bonds on CrIII–O Surface Sites Is a Key Step in Catalytic Polymerization of Ethylene and Dehydrogenation of Propane. Delley, Francisco Núñez-Zarur, Aleix Comas-Vives, and Christophe Copéret. Environmental Science & Technology 2018, 52 Does Soluble Mn(III) Oxidant Formed in Situ Account for Enhanced Transformation of Triclosan by Mn(VII) in the Presence of Ligands?. Yuan Gao, Jin Jiang, Yang Zhou, Su-Yan Pang, Chengchun Jiang, Qin Guo, Jie-Bin Duan.Straightforward Synthesis of Single-Crystalline and Redox-Active Cr(II)-carboxylate MOFs. Leszczyński, Arkadiusz Kornowicz, Daniel Prochowicz, Iwona Justyniak, Krzysztof Noworyta, Janusz Lewiński. This article is cited by 24 publications. These new redox potentials, along with the reinterpretation of literature data, will aid in understanding the redox chemistry involved in Cr(VI/V) oxidations of organic substrates and Cr(VI)-induced cancers. Finally, the equilibria among the Cr(V) or Cr(IV) complexes with excess ligand appear to be due to complexes involving one or two ehba ligands per chromium, as established by the isolation and characterization of the Cr(V) dimer, 2. The structures of the Cr(IV) complexes, 2 -, -, and, have been assigned on the basis of X-ray crystallography for isostructural V(IV) complexes. The spectra of the Cr(IV) complexes were also examined by reduction of - with pulse radiolysis. Most of these potential data differ markedly from those estimated by Ghosh and Gould ( J. By using the values of Cr V/IV and Cr V/III couples, formal potentials for the 2 -/ - and -/ - couples were calculated to be 1.24 and 1.03 V, respectively. Potentiometric titrations using the 4 - reduction of - yielded a formal potential of 0.84 V for the -/ - redox couple. The formal reduction potentials of - /2 - and -/ - (L = ehba = 2-ethyl-2-hydroxybutanoato(2−)) are 0.44 and 0.65 V, respectively, from cyclic voltammetric measurements.